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Synthesis and structure of platinum complexes [Ph4P] +[PtCl3(DMSO)]- and [Ph4P] +[PtCl5(DMSO)]-

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dc.contributor.author Sharutin V.V. en
dc.contributor.author Senchurin V.S. en
dc.contributor.author Sharutina O.K. en
dc.contributor.author Gushchin A.V. en
dc.date.accessioned 2018-10-15T11:17:09Z
dc.date.available 2018-10-15T11:17:09Z
dc.date.issued 2013
dc.identifier.issn 360236
dc.identifier.uri http://dspace.susu.ru/handle/0001.74/19939
dc.description.abstract The reaction of tetraphenylphosphonium chloride with an equimolar amount of potassium tetrachloroplatinate or hexachloroplatinic acid in dimethyl sulfoxide gave the complexes [Ph4P]+[PtCl3(DMSO)] - (I) and [Ph4P]+[PtCl5(DMSO)] - (II), respectively. The phosphorus atoms in the cations have tetrahedral environment, the CPC angles and P-C distances 105.63(13) -112.13(14), 1.795(3)-1.797(3) Å I) and 105.7(3) -112.9(3), 1.783(7)-1.791(6) Å II). The platinum coordination polyhedra in the anions [PtCl3(DMSO)]- and [PtCl5(DMSO)]- are distorted square (Pt-S, 2.1937(8); Pt-Cl, 2.2894(10)-2.3024(10) Å; trans-angles: SPtCl, 177.38(4); ClPtCl, 175.40(4)) and octahedron (Pt-S 2.291(2) Å; Pt-Cl, 2.312(2)-2.334(2) Å, trans-angles: SPtCl, 178.28(9); ClPtCl, 178.80(9) and 178.88(8)). © 2013 Pleiades Publishing, Ltd. en]
dc.language.iso English
dc.relation.ispartof Russian Journal of Inorganic Chemistry en]
dc.subject Equimolar amount en]
dc.subject Phosphorus atom en]
dc.subject Platinum complexes en]
dc.subject Platinum coordination en]
dc.subject Chlorine compounds en]
dc.subject Dimethyl sulfoxide en]
dc.subject Organic solvents en]
dc.subject Platinum en]
dc.subject Synthesis (chemical) en]
dc.subject Platinum compounds en]
dc.title Synthesis and structure of platinum complexes [Ph4P] +[PtCl3(DMSO)]- and [Ph4P] +[PtCl5(DMSO)]- en
dc.type Article en]
dc.identifier.doi 10.1134/S0036023613010191
dc.identifier.scopus https://www.scopus.com/inward/record.uri?eid=2-s2.0-84872415128&doi=10.1134%2fS0036023613010191&partnerID=40&md5=e1e9d5be46dd1153f2c4b979cd55e7c4

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